
Historical Science Replaced Mineral Theories With Biological Nitrogen Fixation
Early agricultural chemistry pitted Justus von Liebig's mineral theory against the empirical field data of John Bennet Lawes and Joseph Henry Gilbert at Rothamsted. Liebig insisted atmospheric ammonia supplied all plant nitrogen, but Rothamsted proved crops require nitrogenous soil amendments. The deadlock broke when Hermann Hellriegel and Hermann Wilfarth demonstrated that leguminous root nodules harbour bacteria capable of fixing free atmospheric nitrogen.

